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The inhibiting properties of corrosion inhibitors of norfloxacin (NFA), ciprofloxacin (CFA), and ofloxacin (OFA) for steel in 1 M HCl solution had been studied, respectively. Their corrosion inhibiting property was performed in 1 mol/L hydrochloric acid by potentiodynamic polarization (PDP) and electrochemical spectroscopy (EIS) tests at different temperatures range. The order of their corrosion inhibition efficiency is as follows: CFA > NFA > OFA. Polarization data suggest that the corrosion inhibitors are predominantly mixed-type. The best fit for inhibitors adsorption is obey Langmuir isotherm model. The structure properties of corrosion inhibitors are correlated by means of a density-functional quantum-chemical approach. Moreover, the molecular dynamics calculation vividly simulates the adsorption behavior of CFA, NFA and OFA molecules on the surface of steel.

international journal of electrochemical science

Corrosion inhibition performance of three antibacterial agents for mild steel in 1 M HCl solution at different temperature: experimental and theoretical studies