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The electrochemical conversion of CO2 into high-value fuels is a promising technique to reduce CO2 emission and relief the crisis of fossil fuel depletion. Here we report the influence of supporting electrolyte on the electrochemical reduction of carbon dioxide catalyzed by cobalt protoporphyrin. Phosphate anion strongly coordinates to the cobalt center leading to the positive movement of Co III /Co II redox peak and the difficulty formation of carbon monoxide. Alkali cations, such as Li + , Na +

Influence of Supporting Electrolyte on the Electrocatalysis of CO2 Reduction by Cobalt Protoporphyrin