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A new modified nano-composite Tm 3+ -carbon paste electrode (CPE) including nanosilica (NS) and multi-walled carbon nanotube (MWCNT) based on N, N'-bis (pyridine-2-carboxamido)-2aminobenzylamine (BPCA) as an ion carrier was costructed. The electrode displays a Nernstian response (19.90.3 mV/decade across a broad range (1.0×10 −8 to 1.0×10 −3 mol L -1 ); a detection limits of 3.9×10 −9 mol L -1 between the pH range of 3.1–8.8 and a fast response time of ~5 s. The proposed Tm 3+ -CPE showed a good Tm 3+ selectivity over a wide variety of cations, including alkali, alkaline earth, transition and heavy metal ions. The created Tm 3+ -CPE was satisfactory applied to the Tm 3+

Construction of a New Modified Nano-Composite Tm3+-Carbon Paste Electrode Based on N, N'-bis (pyridine-2-carboxamido)-2-aminobenzylamine