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Composite material LiNi1/3Co1/3Mn1/3O2 cathode material for lithium-ion battery was obtained with lithium carbonate, nickel (II) oxide, cobalt (II, III) oxide and manganese dioxide as raw materials by high temperature ball milling method. To synthesis the LiNi1/3Co1/3Mn1/3O2 with excellent electrical properties, influence of ball-milling time was analyzed in this paper. Results showed that the best electrochemical performance of LiNi1/3Co1/3Mn1/3O2 was obtained from the test, LiNi1/3Co1/3Mn1/3O2 particles acquired ball-milling temperature at 750°C for 15h, and got performance uniformity of the material. Its initial discharge specific capacity reached 166.6 mAh/g at 0.1 C. The capacity of LiNi1/3Co1/3Mn1/3O2 sample was 157.5 mAh/g, with a capacity retention rate of 94.5% over 50 cycles.

Effects of Sintering Time on the Performance of LiNi1/3Co1/3Mn1/3O2 Synthesized by High Temperature Ball Milling Method