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Pure LiFePO4 with multiple morphologies, such as nanoplate, nanocubes, and self-assembled rose-like structures, were synthesis via hydrothermal process employing surfactant CTAB as soft-template. The addition of surfactant is the key factor for controlling the crystal growth of the particles. Among these products, LiFePO4 nanoplates with preferential direction of b-axis delivers the highest capacity at 0.1C, and the most stable cycle performance, indicating a great advantage of shape-control chemistry in nanomaterials preparation, and showing an enormous potential as cathode materials for highperformance lithium ion batteries.

Controllable Fabrication of LiFePO4 Cathode Materials with Multiple Morphologies for Lithium Ion Batteries