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Synthesis of four new platinum(IV) complexes (C1–C4) with bidentate N,N'-ligand precursors, O,O'-dialkyl esters (L1–L4) (alkyl = ethyl, propyl, butyl and pentyl) of (S,S)-ethylenediamine-N,N'-di-2propanoic acid, H2-S,S-eddp were reported. The platinum(IV) complexes were characterized by elemental analysis and their structures determined on the basis of infra-red, H and C NMR spectroscopy. Cytotoxicity against human breast carcinoma MDA-MB-231, human colon carcinoma HCT-116 and SW-480 tumour cell lines was determined using the MTT assay, which indicated the larger the size of the complex or ligand, the greater the cytotoxicity.

macedonian journal of chemistry and chemical engineering

Part XVI - Stereospecific ligands and their complexes. Synthesis, characterization and in vitro antiproliferative activity of new platinum(IV) complexes with some O,O'-dialkyl esters of (S,S)-ethylenediamine-N,N'-di-2-propanoic acid against breast cancer