English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The kinetics of oxidation of diethylene glycol by ditelluratoargentate (III) in alkaline medium has been studied by using spectrophotometer in the temperatures of 298.2K-318.2K. All data was obtained in the pseudo-first order reaction. The reaction rate showed a first-order for [diethylene glycol]. The observed rates constants (kobs) increased with increasing [reductant] and [OH ], but kobs decreased with the increase of [TeO4 2]. In addition, there is a negative salt effect on the reaction of [diethylene glycol]. A plausible mechanism involving a slow reaction as the rate-controlled step is proposed and the rate equations derived from the mechanism can explain all the experimental results. Thus, the activation parameters at 298.2K were calculated.

Kinetics and Mechanism Study of Oxidation of Diethylene glycol by Ditelluratoargentate (III) in Alkaline Media