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Densities, ultrasonic velocities and Infra-red spectroscopes of binary liquid mixture of ochlorotuluene and p-chlorotoluene with t-butanol have been measured at 308.15 and 313.15 K using these parameter the isentropic compressibilities Ks interrmolecular free length Lf have been calculated. Deviation in isentropic compressibilites ∆Ks and Excess intermolecular free length Lf E are interpreted in terms of hetroassociation. These Derived parameters have been used to study the intermolecular interaction in binary liquid mixtures. The theoretically calculated values of ultrasonic speed are derived by using free length theory. Collision factor theory, Nomoto’s and Van Dael’s equation were compared with those obtained experimentally.

Sonochemical and Infrared Spectroscopies Study of Binary Liquid Mixture of O-Chlorotoluene and P-Chlorotolune with TButanol At 308.15 K and 313.15 K