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Two-dimensional Zn(II) coordination polymer {[Zn(bpdc)(H2O)]·dmf·H2O}n (1), where H2bpdc= 2,2′-bipyridine-4,4′-dicarboxylic acid and dmf= N,N-dimethylformamide, was obtained by hydrothermal synthesis and characterized by IR spectrum and single-crystal X-ray diffraction. The Zn(II) ion is coordinated in a distorted square pyramidal N2O3 environment by two N-atoms from one bpdc 2ligand, two carboxylate oxygen atoms from another two bpdc 2ligands and one water molecule. The crystal lattice of 1 hosts the dmf and water solvent molecules via O-H···O hydrogen bonds with crystal components. The new material reveals blue-orange luminescence upon excitation with ultraviolet light.

A Novel 2d Zinc(II) Coordination Polymer Based on 2,2'-bipyridine-4,4'-dicarboxylic Acid: Synthesis, Crystal Structure and Photoluminescence Property