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Phase equilibrium data for hydrates formed in CO 2 + orange juice system, C 2 H 4 + orange juice system and C 2 H 6 + orange juice system were measured in pressures range of (0.68 to 4.40 MPa) and temperatures range of (274.8 to 283.3 K). The experimental data were generated using an isochoric pressure-search method. The effects of orange juice on the hydrate equilibrium conditions were studied. The hydrate equilibrium conditions were calculated by using the Redlich-Kwong-Soave equation of state with a modified version of the Huron-Vidal mixing rule. It is found that the orange juice exhibited an inhibition effect on hydrate formation. The results of the predicted three-phase equilibrium conditions for the CO 2 , C 2 H 4 and C 2 H 6 hydrate formation in water and orange juice were in good agreement with the experimentally data.

Measurement and Prediction of Hydrate Phase Equilibrium of Orange Juice + CO2, C2H4 or C2H6 for Orange Juice Concentration