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Purification of Gold from Chloride Leach Liquor of Copper Anode Slime by Octanol-Kerosene Organic Extractant
Author(s) -
Nima Sadeghi,
Eskandar Keshavarz Alamdari
Publication year - 2015
Publication title -
mavādd-i pīshraftah dar muhandisī
Language(s) - English
Resource type - Journals
eISSN - 2423-5733
pISSN - 2251-600X
DOI - 10.18869/acadpub.jame.34.2.71
Subject(s) - kerosene , chemistry , copper , chloride , anode , nuclear chemistry , inorganic chemistry , organic chemistry , electrode
In the present study, the copper anode slime was leached in chloride media. Then, pregnant leach solution (PLS) was purified using solvent extraction method and Octanol-kerosene solution. HAuCl4.2L was determined as the extracted macromolecule, and separation of impurities, such as copper, iron and selenium was done in the presence of gold. McCabe-Thiele diagram of Au–HCl (3 M)– Octanol (40% v/v) in O/A=3/4 showed that Au concentration in aqueous phase decreased from the initial value of 200 to 7 mg/L, after 5 stages. Ammonia solution was proposed as the stripper and McCabe-Thiele diagram was presented to obtain the number of gold stripping steps by ammonia solution.

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