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ion is not as simple a process as initially thought (Figure 5). Possibly because of the high affinity of silver towards gold and halogen, various Au-Ag intermediates (A, B, C) are formed during the halogen abstraction step. These intermediates have been isolated and identified (Figure 5). The presence of silver could also have an additional deleterious effect: the formation of a dinuclear gold-silver resting state (i.e., intermediate D in Figure 5).

Synthesis of N-heterocycles through cyclization-triggered tandem additions to alkynes and the study of promoters in ionic reactions.