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Franck-Condon factors factors and r-centroids have been calculated for the G  Φ − X  Φ  , K  Φ  − X  Φ  , L  Φ  − X  Φ  , (20.6)  Γ  − X  Φ  and (34.7)  Γ  − X  Φ  bands of Cobalt monofluoride 59 Co 19 F from the best available molecular constants using Morse and Rydberg- Klein-Rees (RKR) methods. The reliability of the obtained values was verified by comparing the results of five different programs. Based on the calculated Franck-Condon factors values, the appearance of the bands in these systems are discussed and the relationship between the r-centroids and the band-origin wavenumbers and wavelengths are also determined along with accuracy factors.

Franck-Condon Factors and r-Centroids for Several Systems of CoF Molecule