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The relationship between the physicochemical properties of compounds and their inhibition factors  of the atmospheric corrosion of steel are discussed with Schiff and Mannich bases as examples. It is shown that the inhibitive efficiency of compounds can be predicted from correlations between  and calculated parameters such as saturated vapor pressure, total electron density on heteroatoms, and hydrophobicity constant. The predicted and experimental inhibition factors of new inhibitors agree to within ±10%.

international journal of corrosion and scale inhibition

Volatile inhibitors of atmospheric corrosion of ferrous and nonferrous metals II. Prediction of the efficiency of volatile inhibitors of atmospheric corrosion of steel (with Schiff and Mannich bases as examples)