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Localized and autolocalized states and their simplest two-electron complexes in polar media are considered in the continuum approximation. The electron-phonon interaction is taken into account in the Pekar-Fröhlich approximation. The exponentially correlated Gaussian basis is used for the calculation of the energy spectrum of two-electron systems in phonon field. Analytical expressions for effective functionals of paramagnetic centers and their simplest two-electron complexes are presented. Numerical examples are given for the calculations of the energy spectrum of localized and self-localized states in metal-ammonia solutions.

Exponentially Correlated Gaussians for Simulating Of Localized and Autolocalized States in Polar Media