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The purpose was to investigate the formation of complex compounds in heteropolytungtoterbiate-ion solutions and to consider thermodynamic probability of these reactions. Methods and methodology. pH-potentiometry at 25±0.1 °C was used to study interactions within TbW10O36 –H(OH)–H2O system (CTbW O M 10 36 9 1 10 3 = ◊ ). A model describing equilibrium processes in acidic and alkaline areas was selected by using computer program Clinp 2.1. Pitzer equations were used to calculate of the thermodynamic constants of processes in solutions. ТЕРМОДИНАМИЧЕСКАЯ ВЕРОЯТНОСТЬ ПРОЦЕССОВ КОМПЛЕКСООБРАЗОВАНИЯ В РАСТВОРАХ...

ТЕРМОДИНАМИЧЕСКАЯ ВЕРОЯТНОСТЬ ПРОЦЕССОВ КОМПЛЕКСООБРАЗОВАНИЯ В РАСТВОРАХ ПОЛИВОЛЬФРМАТОТЕРБИАТОВ