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ZrMoN films were deposited on a 304 stainless-steel (SS304) substrate with a radio-frequency (RF) reactive magnetron-sputtering system and the properties were changed by adjusting the power of the Mo target. The corrosion behaviors of the ZrMoN films were investigated with potentiodynamic tests and electrochemical impedance spectroscopy (EIS) under the condition of an aerated 0.5M H2SO4 + 1,99 mg/L NaF solution at 70 °C. The results revealed that all samples with ZrMoN films have good hydrophobicity. The XRD test showed that the ZrMoN film is the substitutional solid solution of Mo atoms into ZrN films. As an overall evaluation, the power of the Mo target is 30W. A coated sample displays the best corrosion resistance in the cathode of the PEMFC environment when the power of the Mo target is considered, which indicates that with an increase of the power of the Mo target, the solid solubility also increases; but with a continuous increase of the Mo-target power, the solubility increases and a lattice distortion also occurs, leading to an increase in defects.

ZrMoN films on 304 stainless steel as bipolar plates for PEMFCs using physical-vapor-deposition (PVD) technology