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The catalytic activity and durability for the CO2 reforming of methane was studied on an Ni/Al 2 O 3 catalyst prepared using water-in-oil (w/o) microemulsion. The initial activity of the Ni/Al 2 O 3 catalyst thus prepared was higher than that of an impregnated one. The impregnated catalyst deactivated with time-on-stream due to severe coking. In contrast, the catalyst prepared using w/o microemulsion kept its activity for 50 h and caused little coking at a CO 2 /CH 4 molar ratio above 1.4, The carbon species deposited on the catalyst prepared using w/o microemulsion was less crystallized than that on the impregnated one. The superior resistance of the catalyst to carbon deposition is attributed to the generation of such a carbon species.

Low Carbon Deposition on CO2 reforming of Methane over Ni/Al2O3 Catalysts Prepared Using W/O Microemulsion.