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PEO partitioning from water to CH2Cl2 and CHCl3 increases with its molar mass, leveling off at ca. 3 000 g mol(-1). Such a behaviour is related to PEO end-group contributions, suggesting a polyglycol to polyether transition at ca. 3 000 g mol(-1)

journal of the brazilian chemical society

Poly(ethylene glycol) or Poly(ethylene oxide)?: Magnitude of end-group Contribution to the Partitioning of Ethylene Oxide Oligomers and Polymers between Water and Organic Phases