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Tiofenois reagem com nitro olefinas em meio aquoso dando os correspondentes nitro-sulfetos em 58 - 95 % de rendimento. Este processo leva a formacao, predominante, de produtos anti. Para o caso da nitro olefina ciclica 1-nitro-ciclo-hexeno e observada unicamente a formacao de cis-1-nitro-2-(tio-fenil)-ciclo-hexano. Esta metodologia e interessante porque utiliza-se agua como solvente levando a minimizacao do custo, diminuindo os problemas de toxidez e poluicao ambiental

Organic reaction in water. Part 3¹: diastereoselectivity in Michael additions of thiophenol to nitro olefins in aqueous media