English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The bis(ruthenium)alkyne complex [cis-{RuCl (bpy)(2)(mu-C drop C)}](2) (1) was obtained by treatment of 1 equiv of either 1,4-bis(trimethylsilyl)-1,3-butadiyne or bis(trimetylsilyl)acetylene with 2 equiv of cis-[RuCl2(bpy)(2)]2H(2)O, NaF and NaBF4 salts in methanol/CH2Cl2 mixture (10/1) in 52% and 35% yields, respectively. H-1, (13){H} NMR and principally electrochemical analyses confirmed that the same product was obtained from the two reactions. Cyclic voltammetric analyses of (1) from 0 to 1.20V displays two one-electron quasi-reversible oxidation peaks attributed to the Ru(II)/Ru(III) couple. The redox processes are separated by 520 mV, indicating a significant electronic communication between the two metallic centers

journal of the brazilian chemical society

Synthesis and electrochemical characterization of bimetallic ruthenium complexes with the bridging eta2(&lt;FONT FACE=Symbol&gt;s,s&lt;/FONT&gt;)-1,3-butadiyne-1,4-diyl ligand