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nium(IV) is described. The redox properties of these compounds along with the properties of s imilar bis(η5-cyclopentadienyl)(ene-1,2-dithiolato)titanium(IV) complexes are assessed in neutral solu - tions. All the compounds exhibited a reversible one electron reduction process, the potent ial at which the reduction occurs being dependent on the nature of the dithiolato ligand. A second red uction process is observed on the 2,3-quinoxaline derivatives. The properties of the latter are al so assessed in acidic solution and the presence of H + has a small effect on both processes, suggesting that the same type of event occurs under both conditions.

journal of the brazilian chemical society

Syntheses and Electrochemical Studies of Bis(eta5-Cyclopentadienyl)-(2,3-Quinoxalinedithiolato)Titanium(IV) Derivatives: Comparison with the Electrochemical Properties of Similar Complexes