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Full quantum charge transfer study of the process B3+ + He ® B2+ + He+ has been investigated in the collision energy range 1-102 eV using an ab-initio interaction potential. A new method to solve the Schrodinger equation in an adiabatic basis was used, where the radial and rotational coupling were taken into account, and the importance of the coupling between states of different symmetry was discussed. Moreover, by using the well known Landau-Zener model, it was concluded that the two state model cannot be applied for the present system, and this might indicate that such a model should be applied carefully for other systems when a charge transfer process is considered. Finally, the quantum total cross sections were compared with the previous published work of Gargaud and co-workers and a fair agreement was achieved.

Quantum Charge Transfer Study of Triply Charged Ions in the Adiabatic Representation: the (BHe)3+ System