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The chemical compounds of Cladia aggregata from the states of Paraná and Santa Catarina were analyzed, resulting in five chemotypes. The chemotypes are as follows: barbatic and 4-O-demethylbarbatic acid; barbatic, 4-O-demethylbarbatic, and homosekikaic acid; barbatic, 4-O-demethylbarbatic and diffractaic, or barbatic and diffractaic acid; barbatic, 4-O-demethylbarbatic, and fumarprotocetraric acid; and barbatic, 4-O-demethylbarbatic, and stictic acid

Notes on the chemical variation of the lichenized Ascomycota Cladia aggregata (Cladoniaceae) in the states of Paraná and Santa Catarina, Brazil