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Difficulties to produce waterproof starch based films are widely reported in literature (Golachowski et al., 2015). Starch hydrophilic nature limits its use and new products development (Mbougueng et al., 2012; Raina et al., 2007). Modifications of native starch can be performed to enhance its positive attributes and to reduce shortcomings (Ashogbon & Akintayo, 2014). Starch acetates with high degree of substitution (DS > 1) have been studied for 60 y with the aim of replacing cellulose acetate (Chi et al., 2008).

Effect of the degree of acetylation, plasticizer concentration and relative humidity on cassava starch films properties