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Single-phase Pb(Fe2/3W1/3)O3 (PFW) multiferroic ceramics doped with magnetic ions were fabricated using a modified B-site precursor method. Dielectric response was investigated over a wide range of temperature and frequency. Doping did not modify the characteristic temperatures (TC, TN) and the order at ferroelectric phase transition, keeping the relaxor properties. However, the leakage current and resistivity of PFW have been improved with the substitutions: 1 mol% MnO2 addition caused a significant increase in the electric resistivity of PFW ceramics, around 7 orders of magnitude.

Effect of magnetic ion doping on structural, electric and relaxor properties of Pb (Fe2/3W1/3) O3 multiferroic ceramics