English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

We report sol-gel synthesis, structural characterization and magnetic properties of La 2 Mn 1-x Ti x NiO 6 (0 ≤ x ≤ 1.0). Ti doping removed the biphasic structure of La 2 MnNiO 6 by suppression of rhombohedral structure and all the Ti containing samples crystallized in monoclinic P 2 1 / n symmetry. La 2 MnNiO 6 exhibits multiple magnetic transitions. The high temperature ferromagnetic transition of La 2 MnNiO 6 gradually shifted to lower temperatures with increase in Ti doping. La 2 TiNiO 6 (x = 1.0) does not show any long-range magnetic ordering. The suppression of magnetic transition by Ti doping is ascribed to the destruction of Mn 4+ —O—Ni 2+ superexchange interaction. However, the signature of ferromagnetic phase persists up to 70% Ti doping, indicating the robustness of magnetic ordering in La 2 MnNiO 6 . These results suggest that the addition of Ti 4+ truncates the ferromagnetic Mn 4+ —O—Ni 2+ superexchange path and it likely promotes ferromagnetic cluster formation. The robustness of ferromagnetic state towards Ti substitution compared to the simple perovskite or spinel structure can be attributed to cationic ordering in double perovskite structure. Both the pure and Ti-doped samples exhibit magnetic frustration at lower temperatures due to partial cationic disordering. The absence of long-range ordering in La 2 TiNiO 6 , unlike La 2 TiCoO 6 or Pr 2 TiCoO 6 , could be related to cationic disordering.

Synthesis, structure and magnetic properties of Ti doped La2MnNiO6 double perovskite

Synthesis, structure and magnetic properties of Ti doped La₂MnNiO₆ double perovskite