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A possibility of the triple molybdates formation with both NASICON-like and NaMg 3 In(MoO 4 ) 5 structures in the Ag 2 MoO 4 – A MoO 4 –Ga 2 (MoO 4 ) 3 ( A = Mn, Co, Zn, Ni) systems was studied by powder X-ray diffraction analysis. It was established that NASICON-like phases Ag 1− x A 1− x Ga 1+ x (MoO 4 ) 3 are not formed. The triple molybdates Ag A 3 Ga(MoO 4 ) 5 ( A = Mn, Co, Zn) isostructural to triclinic NaMg 3 In(MoO 4 ) 5 (sp. gr. P `1, Z = 2) were synthesized and characterized. The structure of the obtained compounds was refined for AgZn 3 Ga(MoO 4 ) 5  according to the powder data by the Rietveld method. The structure consists of MoO 4 tetrahedra, couples of edge-shared M (1)O 6 octahedra, and trimers of edge-shared M (2)O 6 -, M (3)O 6 - and M (4)O 6 octahedra, which are linked by the common vertices to form a 3D framework. High-temperature conductivity measurements revealed that the conductivity of AgMn 3 Ga(MoO 4 ) 5 at 500 °С reaches 10 -2 S/cm, which is close to one of the known NASICON-type ionic conductors.

Synthesis, crystal structure and electrophysical properties of triple molybdates containing silver, gallium and divalent metals