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Arsenic diesters have same structural and chemical properties as P i (phosphate) diester. Beside this structural similarity, arsenate is not considered by cellular processes to replace phosphate. Quantum calculation reveals that this happens due to very high hydrolysis rate of As i diester (As–O-bond-based compounds) as compared to P i , but how organoarsenicals (As–C-bond-based compounds) that are produced by alkylation of As i survive in highly aqueous tissues of marine organisms? We found that this alkylation results in lower hydrolysis rate of As i diester. Our work concluded that alkylating effort by our body on As i is to avoid structural ambiguity with phosphate and excrete out arsenic in the form of organoarsenicals from body.

Effect of Alkylation on the Kinetic Stability of Arsenodiester and Organoarsenicals against Hydrolysis: A Theoretical Study