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Decomposition of triphenylbismuth dicrotonate in diffused light in bensene in the presence of spin trap of C-phenyl-N- tert -butylnitrone leads to formation of phenyl radicals which are registered as the adduct PhCH(Ph)N(O•)Bu-t. Triphenylbismuth dicrotonate Ph 3 Bi(O 2 CCH=CHCH 3 ) 2 in benzene solition in the presence of C-phenyl-N- tert -butylnitrone PhCH=N(O)Bu-t decomposes in light. An adduct of phenyl radical and spin trap PhCH(Ph)N(O•)Bu-t was registered by ESR method.

chimica techno acta

<i>Tert</i>-butyl-diphenylmethylnitroxyl radical formation with the reaction of triphenylbismuth dicrotonate and C-phenyl-N-<i>tert</i>-butylnitrone in benzene

Tert-butyl-diphenylmethylnitroxyl radical formation with the reaction of triphenylbismuth dicrotonate and C-phenyl-N-tert-butylnitrone in benzene