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An easily accessible ionic liquid, 1-hexyl-3-methylimidazolium bromide, was synthesized from n-hexyl bromide and N-methylimidazole under microwave irradiation condition, and characterized by 1 H and 13 C NMR, and MS. The ionic liquid was demonstrated to be an efficient and recyclable solvent for the Heck cross-coupling reaction between iodobenzene and styrene to form trans-stilbene as the principal product. The reaction was performed in the ionic liquid, using 5 mol% of PdCl 2 at 140 o C in the presence of triethylamine as the base. Reaction conversions of 60% and 97% were achieved after 7 hours, without and with using triphenylphosphine as an additive, respectively. The ionic liquid – PdCl 2 system could be reused in subsequent reaction without significant degradation in activity. Furthermore, using the ionic liquid as the reaction solvent in conjunction with microwave irradiation, the reaction rate was dramatically enhanced, with 98% conversion being achieved within 2 minutes.

Imidazolium-based ionic liquid as a green solvent for the Heck reaction between iodobenzene and styrene