English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Reactive spark plasma sintering has been utilised as a high-throughput processing route for the synthesis of two simulant zirconolite wasteform materials, targeting Ca 0.80 Ce 0.20 ZrTi 1.60 M 0.40 O 7  (M = Fe 3+  and Al 3+ ). Materials were processed under 15 MPa uniaxial pressure, with heating/cooling rates of 100 °C/min to 1320 °C, maintained under vacuum. Despite moderate yield (&gt; 80 wt%) of zirconolite-2M, a considerable Ce-rich perovskite phase was formed in both formulations, attributed to complete reduction of the Ce inventory to Ce 3+ , as determined by Ce L 3 -edge XANES analysis. The composition charge balanced with Al 3+  was favoured on the basis of lower accompanying perovskite fraction. Graphical abstract

Synthesis and characterisation of Ce-doped zirconolite Ca0.80Ce0.20ZrTi1.60M0.40O7 (M = Fe, Al) formed by reactive spark plasma sintering (RSPS)