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A sample of zirconolite with nominal composition Ca 0.80 Ce 0.20 ZrTi 1.60 Cr 0.40 O 7  was processed via Hot Isostatic Pressing (HIP), with a dwell temperature and pressure of 1320 °C/100 MPa maintained for 4 h. The produced wasteform was characterised by powder XRD, SEM–EDS, Ce L 3  and Cr K-edge XANES. A significant portion of the Ce inventory did not fully partition within the zirconolite phase, instead remaining as CeO 2  within the microstructure. Inspection of the stainless steel–ceramic interface detailed the presence of an interaction region dominated by a Cr-rich oxide layer. No significant Cr or Fe migration was observed, although a greater concentration of perovskite was observed at the periphery, relative to the bulk ceramic matrix. The X-ray absorption features of Cr remained analogous with Cr 3+  accommodation within TiO 6  octahedra in the zirconolite matrix. The absorption edge of Ce was comprised of contributions from zirconolite-2M and unincorporated CeO 2 , with an average oxidation state of Ce 3.9+ . As zirconolite-2M accounted for &gt; 92 wt% of the overall phase assemblage, it is clear that the dominant oxidation state of Ce in this phase was Ce 4+ . Graphic abstract

Synthesis and characterisation of HIP Ca0.80Ce0.20ZrTi1.60Cr0.40O7 zirconolite and observations of the ceramic–canister interface