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Bulk metallic glass forms when liquid metal alloys solidify withoutcrystalization. In the search for Iron-based bulk glass-forming alloys of themetal-metalloid type (Fe-B- and Fe-C-based), crystals based on the structuralprototype C6Cr23 often preempt the amorphous phase. Destabilizing thiscompeting crystal structure could enhance glass-formability. We carry outfirst-principles total energy calculations of enthalpy of formation to identifythird elements that can effectively destabilize C6Cr23. Yttrium appears optimalamong transition metals, and rare earths also are suitable. Atomic size is thedominant factor.Comment: 6 pages, 4 fig

Stability of Fe-Based Alloys With Structure Type C6Cr23

Stability of Fe-Based Alloys With Structure Type C₆Cr₂₃