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New composite structures containing ZnS, CdS nanoparticles were prepared with bright light-blue colour of luminescence. The structures were formed by spraying organic solution of zinc or cadmium ditiocarbamate onto substrates at temperatures within the range 40120°Ñ. It was established that the film emission maximum monotonously shifts into short-wave spectral region at the decreasing substrate temperature: from 590 nm (Òs = 120°Ñ) to 500 nm (Òs = 50°Ñ) for ZnS and from 510 nm (Òs = 120°Ñ) to 450 nm (Òs = 40°Ñ) for CdS. This fact can be explained by the quantum size effect: X-ray analysis has shown that researched films contain crystalline particles of 15 nm size.

Composite film structures containg ZnS, CdS nanoparticles prepared by MOC pyrolysis at low temperatures