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This paper summarizes the results of experimental studies revealing a multimodal character of the function of size distribution of Si nanoclusters in light-emitting SiO 2 :Si structures. To explain the nature of this multimodality, a «liquid» approach to the description of the coalescence stage based on taking into account the correlation effects caused by particle-particle interactions in the space of sizes is proposed. This approach is justified by a high concentration of solutions where the nuclei of the new phase are described by a multimodal function of size distribution.

Multimodal size distribution of Si nanoclusters in SiO2 as manifestation of interaction in the space of sizes