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Volatile components in Russula rubra (Krombh.) Bres. were determined with the use of a solid-phase microextraction (SPME)/gas chromatography-mass spectrometry (GC-MS) method. The compounds were identified by the automatic mass spectral deconvolution and identification system (AMDIS) and Kováts retention index (RI). Under the optimized conditions of GC-MS, 52 volatile components were identified in Russula rubra, with the relative percentage accounting for 80.2% of the total ion peak. Notably, aristolone (20.4%), benzaldehyde (20.2%), geranyl acetone (11.0%), and 3-octanone (10.7%) were all at higher levels in samples. The main identified compounds were aldehydes, ketones, alcohols, ethers, and alkanes.

SPME-GCMS combined AMDIS and KOVÁTS retention index to analyze the volatile organic compounds in Russula rubra (Krombh.) Bres. essential oil