English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The  S  1 ( 1  B  2 ) ←  S  0 ( 1  A  1 ) electronic transition of anisole and the anisole/CO 2  aggregate cooled in a supersonic free jet has been investigated in detail using REMPI spectroscopy and quantumchemical model calculations. The 42 intramolecular modes of anisole in the  1  S  1  state are assigned. Some previous assignments of modes of anisole in the  1  S  1  state have been improved, some of the assignments are still tentative. The origin of the corresponding electronic transition in the 1:1-aggregate is blueshifted by 117cm −1  versus the 0-0 transition of anisole, the origine in the 1:2-agreggate is redshifted by 216cm −1 . Probably a second conformer of the 1:1-aggregate is formed in the molecular beam. 36 fundamental modes of the anisole/CO 2  1:1-cluster out of possible 46 intramolecular modes are assigned. Spectral shifts of the fundamental modes in the  1  S  1  state of anisole/CO 2  due to the aggregation have been observed. The intermolecular modes and their binary combinations with intramolecular modes have been analyzed.

The Absorption Spectrum of Anisole and the Anisole/CO 2 1:1-Cluster. The Influence of Intermolecular Interaction on Intramolecular Vibrations