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Vaporization enthalpies for a pairs of the ionic liquids (ILs) 1,2,3-trimethyl- imidazolium  and 1,2,3-trimethyl- benzimidazolium  bistrifluorsulfonylimide and the corresponding molecular liquids 1,2-dimethyl- imidazole  and 1,2-dimethyl- benzimidazole  were determined using a quartz crystal microbalance method and TGA (for ILs) and the transpiration method (for molecular compounds). Differences in vaporization enthalpies in molecular and ionic liquids are discussed in context of structure-property relations.

Structure-Property Relations in Ionic Liquids: 1,2,3-Trimethyl- imidazolium and 1,2,3-Trimethyl- benzimidazolium bis-(trifluorsulfonyl)imide