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The IR spectrum of benzene and benzene dimer embedded in superfluid helium droplets in the region of the C–H stretch vibration (3000–3110 cm -1 ) was observed. By analyzing the pressure dependence of the spectra it was possible to assign these spectra to benzene monomer and dimer.

High Resolution IR Spectroscopy of the C–H Stretch Bands of Benzene Monomer and Dimer in Helium Nanodroplets