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From extraction experiments and  γ -activity measurements, the extraction constants corresponding to the general equilibrium C + (aq) + I − (aq) ⇔ C + (org) + I − (org) taking place in the two-phase water–phenyltrifluoromethyl sulfone (abbrev. FS 13) system (C +  = organic cation; aq = aqueous phase, org = FS 13 phase) were evaluated. Furthermore, the individual extraction constants of 8 univalent organic cations in the mentioned two-phase system were calculated.

Individual Extraction Constants of Some Univalent Organic Cations in the Two-Phase Water–Phenyltrifluoromethyl Sulfone System