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Fairly monodisperse “dog bone” shaped gold nanorods were obtained clean and in high yield. Their average aspect ratio could be adjusted from ∼ 2 to ∼ 3 by altering the amount of silver nitrate present in the growth solution. They were coated with a uniform, ultrathin shell of silica and used to detect parathion pesticide on an orange peel by shell-isolated nanoparticle-enhanced Raman spectroscopy (SHINERS).

Shell-Isolated Nanoparticle-Enhanced Raman Spectroscopy (SHINERS) Based on Gold-Core Silica-Shell Nanorods