English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The crystal structure of anhydrous cadmium hexacyanoferrate (II), Cd 2 [Fe(CN) 6 ], has been solved from powder diffraction data using information extracted from low resolution radial distribution function. Such anhydrous solid is obtained by soft heating of its parent octahydrate. The radial distribution function proves to be useful for observing changes in heavy atoms interatomic distances in the structure during phase transition related to the material dehydration process. These distances were then used for guessing the heavy atom positions from the direct methods results. Cd 2 [Fe(CN) 6 ] crystallizes in the hexagonal system, space group  P - 3  (147) and cell parameters:  a  = 6.32046(5) and  c  = 6.33786(10)Å. The structure was refined to final agreement factors of  R  wp  = 6.26% and  S  = 1.99. The proposed structural model is supported by the obtained information from Mössbauer, IR and Raman spectra.

Bifurcated CN Group in Hexacyanometallates, the Case of Cd 2 [Fe(CN) 6 ]. Structure Determination from a Combination of RDF and Direct Methods