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For the first time, intracomplex electron transfer reactions were tested in cytochrome  c  based nanohybrids ( i.e. , Fe(II)Cyt C  and Fe(III)Cyt C ), to which polyanionic C 60  derivatives were electrostatically associated. Successful radical ion pair formation, namely, oxidized FeCyt C  and reduced C 60 , was detected when divalent Fe(II)Cyt C  is used. The so formed Fe(III)Cyt C  · C 60  •−  lives for 2.4 ± 0.5 μs.

Iron Cytochrome C Nanohybrids – Supramolecular Electron Transfer to an Electron Accepting Fullerene