English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

A novel empirical model for the diffuse double layer is found by generalizing the simple analytical equations of Gouy–Chapman theory. Two adjustable parameters are introduced into the Boltzmann equation for the exponential dependence of the ion–wall correlation functions on the diffuse layer potential. Optimal parameter values and model validation for 1:1 and 2:1 electrolytes are provided by Monte Carlo simulations. Simple relationships are obtained between these empirical parameters and those commonly associated with the mean-spherical approximation. The new empiricism accurately models diffuse layer potential profiles and ion–wall correlation functions for a restricted 1:1 electrolyte in a primitive solvent.

An Empirical Approach to Modeling Ion Size Effects in Diffuse Double Layer Theory