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Volatile organic compounds (VOCs) can be separated from aqueous micellar surfactant solutions with high efficiency by pervaporation processes using organophilic polymer membranes. This seems to be a surprising result because the transmembrane flux of a VOC strongly depends on its volatility, which is rather low in the presence of a surfactant at concentrations far above the critical micellar concentration.

Separation of Organic Compounds from Surfactant Solutions by Pervaporation. The Influence of a Micellar Phase on Mass Transfer