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Molar conductances of Bu 4 NBPh 4 , Bu 4 NClO 4 , Bu 4 NI, Bu 4 NBr, Bu 4 NCF 3 COO, Pr 4 NBr, Et 4 NI, Et 4 NBPh 4 , NaClO 4 , NaBPh 4 , [Cu(CH 3 CN) 4 ]ClO 4  and CF 3 COOAg have been measured in the concentration range (1–120) × 10 −4  mol dm −3  in acetonitrile (AN) and binary mixtures of AN with  n -butyronitrile ( n -BTN) and DMA. The conductance data in all cases have been analyzed by the Shedlovsky method to evaluate Λ o  and  K  A  of these electrolytes. Some of these salts are associated in these solvent systems. Ion-association in case of silver (I) salts is the largest and relatively more in case of AN + DMA mixtures. Limiting ion conductances (λ i  o ) and hence actual solvated radii ( r  i ) in all solvent systems have been evaluated using a modified form of Stoke's law. Cu + , Ag +  and Na +  are highly solvated, CF 3 COO − , ClO 4  − , Br −  and I −  are poorly/moderately solvated and tetraalkylammonium ions (R 4 N + ) and Ph 4 B −  are not solvated in AN +  n -BTN and AN + DMA mixtures.

zeitschrift für physikalische chemie

Ion-Association and Solvation of Some Copper (I), Silver (I) and Tetraalkylammonium Salts in Binary Mixtures of Acetonitrile with  n -Butyronitrile and N,N-Dimethylacetamide