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Various protonation parameters (p K  BH +  , φ and  m  * ) of weak organic bases, N-aryhydroxamic acids have been determined following the Bunnett–Olsen method and Excess Acidity method in perchloric acid solutions. Thermodynamic parameters (Δ G °, Δ H ° and Δ S °) of protonation reaction are also computed. These data are based on p K  BH +   values, derived from Excess Acidity method. Interaction parameters, viz. values of activity coefficients and Setschenow constants of these reagents have been evaluated to explain the salting-in behaviour of the system.

Protonation and Salting-in Behaviour of Weak Organic Bases in HClO 4