English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The thermodyamic dissociation constants for isoelectric reaction of the type LH +  ⇔ L + H +  (where L = 2,2’-bipyridine or 1,10-phenanthroline) have been determined pH-metrically at 298 K in acetone + water mixtures (0-90% of acetone). The pK-values were found to pass through a minimum at about 64-74 Wt% of acetone and then increase. The data are utilized to calculate the Gibbs energies of transfer of the H +  ion from water to acetone + water mixtures from which inferences have been made regarding structural variations and solvent basicity of aquo-organic mixtures.

zeitschrift für physikalische chemie

Studies on Thermodynamic Dissociation Constants of 2,2’-Bipyridine, or 1,10-Phenanthroline in Acetone + Water Mixtures and Gibbs Energy of Transfer of the Hydrogen Ion from Water to Acetone + Water Mixtures