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The reaction NH 2  + H 2  → NH 3  + H (11) was investigated behind shock waves in the temperature range from 1360 to 2130 K. Time histories of NH 2  were measured by frequency modulation (FM) spectroscopy. The rate constant was determined to be  k  11  = 4.5 · 1013 · exp[-61 kJ mol -1 / RT ] cm 3  mol -1  s -1  (Δlog  k  11  = ±0.15, Δ E  a  = ±9 kJ/mol).

Direct Measurements of the Reaction NH 2 + H 2 → NH 3 + H at Temperatures from 1360 to 2130 K